| Material Safety Data Sheet
- Stabilant 22A (TM) - Expires 01/02/2013 |
Manufactured by.- D.W. ELECTROCHEMICALS LTD 
-
3-97 Newkirk Road North, (Unit 3)
-
Richmond Hill, Ontario L4C 3G4
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CANADA
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Phone: (905) 508-7500
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Fax: (905) 508-7502
| SOME FIRE HAZARD SOME HEALTH
HAZARD |
(WHMIS Classification B-2, D-2B)
DESIGNATION
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Name: Stabilant 22A - (No synonyms
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Product Use: Electric Contact Enhancer
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Family: 75% Alcohol - 25% Polyglycol
Family Name & Identity
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75% Isopropanol [Fire & Some Health Hazard
- CAS 67-63-0]-20% Stabilant 22 -[No Fire or Health Hazard] - falls under
CAS 9003-11-6 (a Modified Polyoxypropylene-Polyoxyethylene Block Polymer
of the, Polyglycol Family
HAZARDOUS INGREDIENTS:
PHYSICAL DATA
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Physical State: Liquid
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Appearance: Thin clear liquid
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Odor: Sharp alcohol odor
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Odor Threshold: No Data
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Melting Point: -89º Celsius
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Boiling Point: 82.4º Celsius
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Specific Gravity: 0.838
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Decomposition Temp: No Tests Run
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Solubility in water: >500 grams/liter
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Viscosity: No Tests Run
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Vapor Density: 2.01
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Vapor Pressure(mm): 33 mmHg @ 20º
Celsius
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Evaporation Rate: No Tests Run
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Refractive Index: No Tests Run
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Coefficient of Water/oil distribution:
No Tests Run
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pH: Not Applicable
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VOC: 75 % (reportable)
FIRE & EXPLOSION HAZARDS
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Upper Explosion Limit (% by Volume):
12.0
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Lower Explosion Limit (% by Volume):
2.0
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Autoignition Temperature: 399º
Celsius
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Flash Point [Method]: 13' Celsius [Tag
C.C.]
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Hazardous Combustion Products: No Data
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Extinguishing Media: Water fog, C02,
Foam, Dry Chemical
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Special Procedures: Do not use direct
water stream as this could spread the fire. Self Contained Breathing Apparatus
should be used when fighting a fire in a confined area or when exposed
to contamination products.
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Explosion Data - Sensitivity to impact:
No Tests Run
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Sensitivity to Static Discharge: No
Tests Run
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Unusual Fire & Explosion Hazards:
Improperly Disposed of Stabilant soaked combustible materials might be
subject to spontaneous combustion. Heat may build internal pressure in
container, leading to rupture of container.
HEALTH EFFECTS DATA
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As the material is 75% isopropanol it exhibits
all of the health hazards of isopropanol but to a lesser degree. The lower
concentration of the isopropanol mitigates the defatting and drying effects
of the near absolute alcohol's on the skin although there is still a hazard
on eye contact. If the container of Stabilant 22A is left uncapped for
extended periods at normal room temperatures, the isopropanol will evaporate
reducing the hazards somewhat. When applied to contacts the isopropanol
will evaporate leaving the nonvolatile portion of the material (Stabilant
22) on the surfaces, and reference should be made to the MSDS for Stabilant
22 as to the potential hazards of that product.
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LD50 (oral, rat):
5000 mg/kg.
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Skin irritation: LC 50
(skin, rabbit 12800 mg/Kg.) The material is a mild irritant and may
cause defatting and drying of the skin.
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Prolonged Skin Exposure: Prolonged
and repeated contact may cause dermatitis.
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First Aid on Skin Exposure: Major spills
on clothing require removal of contaminated clothing, then flush area with
running water and wash with soap and water. Small area contact, wash with
running water, then soap and water. Obtain medical advice.
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Eye irritation: The vapor is a mild
irritant which may cause conjunctivitis and corneal damage. The liquid
is a severe eye irritant which may cause permanent eye damage.
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First Aid on Eye Exposure: Flush eyes
with running water for at least 20 minutes holding eyelids open. Obtain
medical attention immediately! Treat for isopropanol exposure.
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Exposure when Inhaled: LC50
(inhalation, rat , 16000ppm/8H) May cause irritation of the eyes, nose
and throat and of the respiratory tract. Overexposure could cause Central
Nervous System Depression characterized by headache, dizziness, drowsiness,
nausea, vomiting, abdominal pain and incoordination. Severe overexposure
could lead to coma and possibly death due to respiratory failure. Remove
to fresh air. If not breathing give artificial respiration. Obtain medical
attention immediately.
-
First Aid oral ingestion: If victim
is
alert and not convulsing, rinse out mouth and give 1/2 to 1 glass of water
to dilute material. DO NOT induce vomiting. If spontaneous vomiting occurs,
have victim lean forward with head down to avoid breathing in of vomitus,
rinse mouth and administer more water--Transport victim to an emergency
facility IMMEDIATELY!
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Emergency Medical Care: Extreme care
must be taken to avoid aspiration of product into lungs, which may result
in pulmonary edema.
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Exposure Limits: No Tests Run
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Sensitization to Material: Limited
tests indicate no sensitization effects
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Carcinogenicity: None Known.
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Reproductive Effects: No Tests Run.
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Tetratogenicity: No Tests Run.
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Mutagenicity: No Tests Run.
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Synergistic Materials: None Known.
REACTIVITY DATA
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Stability under normal conditions:
Stable
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Stability under fire conditions: Flammable
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Conditions to avoid: Excessive Temperatures,
sparks, open flames and all other sources of ignition.
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Incomparability: Strong oxidizers,
also may react with aluminum at high temperatures
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Hazardous Decomposition Products: CO,
C02
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Hazardous Polymerization or Reactivity:
Avoid oxidizing materials. Can react violently with potassium oxides and
potassium. Can ignite in contact with platinum black catalyst.
ECOLOGICAL DATA:
-
Biodegradability: No Tests Run - No
Data
-
Fish Toxicity: Harmful to aquatic life
at low concentrations. No quantitative data known.
-
Bacterial Inhibition in Influent: No
Data
ENGINEERING CONTROLS & SPECIAL PROTECTION
INFORMATION
Note: Conditions of use, adequacy
of engineering or of other control measures and actual exposure will dictate
the need for specific protective devices at the workplace. The recommendations
listed in this section indicate the type of equipment which will prevent
overexposure to the product.
-
Ventilation: Where the material is
being applied by swab or small brush, or from a dropper bottle, it is highly
unlikely that sufficient air concentration of the isopropanol could occur
under normal ventilation such that a health hazard could be created. Whenever
large volumes of the material are being used (>250 mL) or whenever the
continually exposed surface area of the material is in excess of 3 Square
ft., it is suggested that local exhaust ventilation be provided.
-
Respiratory Protection: Where small
amounts are being used with a swab or small brush, or are being dispensed
from a dropper bottle, respiratory protection is not needed under normal
ventilation conditions. Where large volumes of the material (>250 mL) are
being used or where large surface areas are being exposed (e.g. - dipping
tanks) the use of a NIOSH/MSHA approved air purifying respirator equipped
with organic vapor cartridges be used if exposed to concentrations up to
1000 ppm. Use an air supplied unit if exposed to higher or unknown concentrations.
(Such as in bulk handling)
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Protective Gloves: Rubber, or Neoprene
gloves should be worn when the handling of circuit boards or connectors
requires constant skin contact with the material.
-
Eye Protection: Goggles or Face shield
when there is a potential for eye contact.
-
Footwear: Non slip when handling bulk
amounts.
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Clothing: Rubber or Neoprene protective
clothing when handling bulk amounts
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Other: Not required
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Bulk Handling: Ground equipment to
prevent static discharge accumulation Observe physical safety procedures
commensurate with the size of the container involved.
SPECIAL STORAGE PRECAUTIONS
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Storage Procedures: Store in a cool,
dry, well ventilated location away from strong oxidizers.
SPECIAL SHIPPING DESCRIPTION (Under the
TDG Act)
Special Shipping Information:
-
Shipping Name: Stabilant 22A - Isopropanol
NOTE.- As 75% of material is Isopropanol, the material should be treated
as Isopropanol for shipment using:
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PIN (Product ID#) UN1219--Packing Group
- II--Class 3:
OTHER REGULATORY INFORMATION
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United States Customs: The quantity
of materials in this product have been reviewed and are not reportable
under SARA title III.
(These materials sre listed on the TSCA Inventory)
OSHA (29CFR1900.1200) Classification:
Flammable Liquid, Eye Irritant
-
Canada: These materials
are listed in the Domestic Substance List under the CEPA.
NCSL not listed
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Customs: For tariff purposes the material
is classified as Semiconductor,other. Harmonized Code # 8541.50.00.80
FIRST AID - EMERGENCY
-
Eyes: Flush eyes with running water
for at least 20 minutes holding eyelids open. Obtain medical attention
immediately! Treat for isopropanol exposure.
-
Skin: Wash with soap and water. Remove
and launder contaminated clothing before re-use. Consult a physician if
irritation develops at site of exposure.
-
Ingestion: If victim is alert and not
convulsing, rinse out mouth and give 1/2 to 1 glass of water to dilute
material.
-
DO NOT induce vomiting!
-
If spontaneous vomiting occurs, have victim
lean forward with head down to avoid breathing in of vomitus, rinse mouth
and administer more water.
-
Transport victim to an emergency facility
IMMEDIATELY!
-
Inhalation: Remove to fresh air. If
not breathing give artificial respiration. Obtain medical attention immediately.
HOUSEKEEPING PROCEDURES
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Clean-up of Leaks & Spills: Eliminate
all sources of ignition. Stop or reduce discharge if safe to do so. Prevent
from entering water courses or sewers. Ventilate enclosed spaces. Contain
by applying absorbent. Collect waste absorbent for disposal. For significant
releases contact regulatory authorities.
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Deactivating Chemicals: None known.
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Disposal of Waste: Dispose of waste
materials in an approved incinerator or waste treatment/disposal facility
in accordance with applicable regulations. Do not dispose of in sewer or
with normal waste.
OTHER DATA (Excluded from waiver at end
of MSDS)
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Heavy Metals: D.W. Electrochemicals
Ltd. has a policy of not allowing any intentional addition of any heavy
metals, such as lead, cadmium, mercury, or hexavalent chromium, or their
compounds, to be used in inks or in the labels on our packaging and requires
the total concentration of these materials, if present, to be so at a level
of less than 100 parts per million and we so certify.
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RoHS Legislation Article 4(1) pertaining
to Heavy Metals in Stabilants and other prohibited components:
D.W. Electrochemicals Ltd. has a policy of not allowing any addition of
any heavy metals, such as lead, cadmium, mercury, or hexavalent chromium,
or their compounds, to be used in the Stabilants and requires the total
concentration of these materials, if present, to be so at a level of less
than 100 parts per million and we so certify. Nor does Stabilant contain
any polybrominated biphenyls (PBBs) or polybrominated diphenyl ethers (PBDEs)
and we so certify.
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Ozone Depleting Chemicals: Because
of our corporate opposition to the use of ODC's either in the manufacture
of, or as an inclusion in any of our products, D.W. Electrochemicals Ltd.
has consistently refused to provide any of our products in aerosol spray
packaging and/or to supply any of our materials diluted with any Class
1 ODC, and we so certify.
-
PCB's: We certify that this material
has been subjected to tests capable of detecting PCB's to a level of less
than 2 parts per million and no PCB's have been found.
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Packaging: New standards are in place
in an attempt to reduce the amount of plastics, tape and/or adhesives used
and to ensure that our packaging may be reused or recycled
MSDS PREPARATION DATA & EMERGENCY PHONE
NUMBER
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Prepared By: Wm Wright
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Department: Engineering
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Preparation Date: January 2nd, 2010
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Current Revision: Revision 23 Updated,
and for inclusion on the web page
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Emergency Phone: (905) 508-7500
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Emergency Contact: Wm Wright
Revision 23
Patented Canada 1987,
US Patent 4696832. Others Pending.
The Stabilants, and the term
"Contact Enhancer" © Copyrighted 1983.
NATO/CAGE Supplier code #38948
15 mL Stabilant 22A has NATO Stock Number
5999-21-900-6937
D.W. Electrochemicals Ltd.
urges each customer or recipient of this MSDS to study it carefully to
become aware of/and understand the hazards associated with the product.
The reader should consider consulting reference works or individuals who
are experts in ventilation, toxicology or fire prevention, as necessary
or appropriate to use and understand the data contains in this MSDS.
To promote safe use and handling
of this product, each customer or recipient should (1) notify employees,
agents, contractors and others who may use this material, of the information
in this MSDS and any other information regarding hazards or safety, (2)
Furnish this same information to each customer for the product, and (3)
request customers to notify their employees customers, and other users
of the product of this information.
The information and recommendations
contained herein are based on data believed to be correct, however no guarantee
or warranty of any kind, expressed or implied, is made with respect to
information and recommendations contained herein except when certified
Please refer
to Technical Note 1 - MSDS for Stabilant 22
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