| Material Safety Data Sheet - Stabilant 22A (TM)
- Expires 01/02/2009 |
Manufactured by.- D.W. ELECTROCHEMICALS LTD 
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3-97 Newkirk Road North, (Unit 3)
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Richmond Hill, Ontario L4C 3G4
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CANADA
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Phone: (905) 508-7500
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Fax: (905) 508-7502
| SOME FIRE HAZARD SOME HEALTH HAZARD |
(WHMIS Classification B-2, D-2B)
DESIGNATION
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Name: Stabilant 22A - (No synonyms
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Product Use: Electric Contact Enhancer
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Family: 80% Alcohol - 20% Polyglycol
Family Name & Identity
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80% Isopropanol [Fire & Some Health Hazard - CAS 67-63-0]-20% Stabilant
22 -[No Fire or Health Hazard] - falls under CAS 9003-11-6 (a Modified
Polyoxypropylene-Polyoxyethylene Block Polymer of the, Polyglycol Family
HAZARDOUS INGREDIENTS:
PHYSICAL DATA
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Physical State: Liquid
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Appearance: Thin clear liquid
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Odor: Sharp alcohol odor
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Odor Threshold: No Data
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Melting Point: -89º Celsius
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Boiling Point: 82.4º Celsius
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Specific Gravity: 0.838
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Decomposition Temp: No Tests Run
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Solubility in water: >500 grams/liter
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Viscosity: No Tests Run
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Vapor Density: 2.01
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Vapor Pressure(mm): 33 mmHg @ 20º Celsius
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Evaporation Rate: No Tests Run
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Refractive Index: No Tests Run
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Coefficient of Water/oil distribution: No Tests Run
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pH: Not Applicable
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VOC: 80 % (reportable)
FIRE & EXPLOSION HAZARDS
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Upper Explosion Limit (% by Volume): 12.0
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Lower Explosion Limit (% by Volume): 2.0
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Autoignition Temperature: 399º Celsius
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Flash Point [Method]: 13' Celsius [Tag C.C.]
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Hazardous Combustion Products: No Data
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Extinguishing Media: Water fog, C02, Foam, Dry Chemical
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Special Procedures: Do not use direct water stream as this could
spread the fire. Self Contained Breathing Apparatus should be used when
fighting a fire in a confined area or when exposed to contamination products.
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Explosion Data - Sensitivity to impact: No Tests Run
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Sensitivity to Static Discharge: No Tests Run
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Unusual Fire & Explosion Hazards: Improperly Disposed of Stabilant
soaked combustible materials might be subject to spontaneous combustion.
Heat may build internal pressure in container, leading to rupture of container.
HEALTH EFFECTS DATA
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As the material is 80% isopropanol it exhibits all of the health hazards
of isopropanol but to a lesser degree. The lower concentration of the isopropanol
mitigates the defatting and drying effects of the near absolute alcohol's
on the skin although there is still a hazard on eye contact. If the container
of Stabilant 22A is left uncapped for extended periods at normal room temperatures,
the isopropanol will evaporate reducing the hazards somewhat. When applied
to contacts the isopropanol will evaporate leaving the nonvolatile portion
of the material (Stabilant 22) on the surfaces, and reference should be
made to the MSDS for Stabilant 22 as to the potential hazards of that product.
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LD50 (oral, rat): 5000 mg/kg.
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Skin irritation: LC 50 (skin, rabbit 12800
mg/Kg.) The material is a mild irritant and may cause defatting and
drying of the skin.
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Prolonged Skin Exposure: Prolonged and repeated contact may cause
dermatitis.
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First Aid on Skin Exposure: Major spills on clothing require removal
of contaminated clothing, then flush area with running water and wash with
soap and water. Small area contact, wash with running water, then soap
and water. Obtain medical advice.
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Eye irritation: The vapor is a mild irritant which may cause conjunctivitis
and corneal damage. The liquid is a severe eye irritant which may cause
permanent eye damage.
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First Aid on Eye Exposure: Flush eyes with running water for at
least 20 minutes holding eyelids open. Obtain medical attention immediately!
Treat for isopropanol exposure.
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Exposure when Inhaled: LC50 (inhalation, rat , 16000ppm/8H)
May cause irritation of the eyes, nose and throat and of the respiratory
tract. Overexposure could cause Central Nervous System Depression characterized
by headache, dizziness, drowsiness, nausea, vomiting, abdominal pain and
incoordination. Severe overexposure could lead to coma and possibly death
due to respiratory failure. Remove to fresh air. If not breathing give
artificial respiration. Obtain medical attention immediately.
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First Aid oral ingestion: If victim is alert and not convulsing,
rinse out mouth and give 1/2 to 1 glass of water to dilute material. DO
NOT induce vomiting. If spontaneous vomiting occurs, have victim lean forward
with head down to avoid breathing in of vomitus, rinse mouth and administer
more water--Transport victim to an emergency facility IMMEDIATELY!
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Emergency Medical Care: Extreme care must be taken to avoid aspiration
of product into lungs, which may result in pulmonary edema.
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Exposure Limits: No Tests Run
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Sensitization to Material: Limited tests indicate no sensitization
effects
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Carcinogenicity: None Known.
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Reproductive Effects: No Tests Run.
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Tetratogenicity: No Tests Run.
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Mutagenicity: No Tests Run.
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Synergistic Materials: None Known.
REACTIVITY DATA
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Stability under normal conditions: Stable
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Stability under fire conditions: Flammable
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Conditions to avoid: Excessive Temperatures, sparks, open flames
and all other sources of ignition.
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Incomparability: Strong oxidizers, also may react with aluminum
at high temperatures
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Hazardous Decomposition Products: CO, C02
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Hazardous Polymerization or Reactivity: Avoid oxidizing materials.
Can react violently with potassium oxides and potassium. Can ignite in
contact with platinum black catalyst.
ECOLOGICAL DATA:
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Biodegradability: No Tests Run - No Data
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Fish Toxicity: Harmful to aquatic life at low concentrations. No
quantitative data known.
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Bacterial Inhibition in Influent: No Data
ENGINEERING CONTROLS & SPECIAL PROTECTION INFORMATION
Note: Conditions of use, adequacy of engineering or of other
control measures and actual exposure will dictate the need for specific
protective devices at the workplace. The recommendations listed in this
section indicate the type of equipment which will prevent overexposure
to the product.
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Ventilation: Where the material is being applied by swab or small
brush, or from a dropper bottle, it is highly unlikely that sufficient
air concentration of the isopropanol could occur under normal ventilation
such that a health hazard could be created. Whenever large volumes of the
material are being used (>250 mL) or whenever the continually exposed surface
area of the material is in excess of 3 Square ft., it is suggested that
local exhaust ventilation be provided.
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Respiratory Protection: Where small amounts are being used with
a swab or small brush, or are being dispensed from a dropper bottle, respiratory
protection is not needed under normal ventilation conditions. Where large
volumes of the material (>250 mL) are being used or where large surface
areas are being exposed (e.g. - dipping tanks) the use of a NIOSH/MSHA
approved air purifying respirator equipped with organic vapor cartridges
be used if exposed to concentrations up to 1000 ppm. Use an air supplied
unit if exposed to higher or unknown concentrations. (Such as in bulk handling)
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Protective Gloves: Rubber, or Neoprene gloves should be worn when
the handling of circuit boards or connectors requires constant skin contact
with the material.
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Eye Protection: Goggles or Face shield when there is a potential
for eye contact.
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Footwear: Non slip when handling bulk amounts.
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Clothing: Rubber or Neoprene protective clothing when handling bulk
amounts
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Other: Not required
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Bulk Handling: Ground equipment to prevent static discharge accumulation
Observe physical safety procedures commensurate with the size of the container
involved.
SPECIAL STORAGE PRECAUTIONS
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Storage Procedures: Store in a cool, dry, well ventilated location
away from strong oxidizers.
SPECIAL SHIPPING DESCRIPTION (Under the TDG Act)
Special Shipping Information:
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Shipping Name: Stabilant 22A - Isopropanol NOTE.- As 80% of material
is Isopropanol, the material should be treated as Isopropanol for shipment
using:
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PIN (Product ID#) UN1219--Packing Group - II--Class 3:
OTHER REGULATORY INFORMATION
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United States Customs: The quantity of materials in this product
have been reviewed and are not reportable under SARA title III.
(These materials sre listed on the TSCA Inventory)
OSHA (29CFR1900.1200) Classification:
Flammable Liquid, Eye Irritant
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Canada: These materials are listed in the Domestic Substance
List under the CEPA.
NCSL not listed
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Customs: For tariff purposes the material is classified as Semiconductor,other.
Harmonized Code # 8541.50.00.80
FIRST AID - EMERGENCY
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Eyes: Flush eyes with running water for at least 20 minutes holding
eyelids open. Obtain medical attention immediately! Treat for isopropanol
exposure.
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Skin: Wash with soap and water. Remove and launder contaminated
clothing before re-use. Consult a physician if irritation develops at site
of exposure.
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Ingestion: If victim is alert and not convulsing, rinse out mouth
and give 1/2 to 1 glass of water to dilute material.
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DO NOT induce vomiting!
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If spontaneous vomiting occurs, have victim lean forward with head down
to avoid breathing in of vomitus, rinse mouth and administer more water.
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Transport victim to an emergency facility IMMEDIATELY!
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Inhalation: Remove to fresh air. If not breathing give artificial
respiration. Obtain medical attention immediately.
HOUSEKEEPING PROCEDURES
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Clean-up of Leaks & Spills: Eliminate all sources of ignition.
Stop or reduce discharge if safe to do so. Prevent from entering water
courses or sewers. Ventilate enclosed spaces. Contain by applying absorbent.
Collect waste absorbent for disposal. For significant releases contact
regulatory authorities.
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Deactivating Chemicals: None known.
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Disposal of Waste: Dispose of waste materials in an approved incinerator
or waste treatment/disposal facility in accordance with applicable regulations.
Do not dispose of in sewer or with normal waste.
OTHER DATA (Excluded from waiver at end of MSDS)
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Heavy Metals: D.W. Electrochemicals Ltd. has a policy of not allowing
any intentional addition of any heavy metals, such as lead, cadmium, mercury,
or hexavalent chromium, or their compounds, to be used in inks or in the
labels on our packaging and requires the total concentration of these materials,
if present, to be so at a level of less than 100 parts per million and
we so certify.
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RoHS Legislation Article 4(1) pertaining to Heavy Metals in Stabilants
and other prohibited components: D.W. Electrochemicals
Ltd. has a policy of not allowing any addition of any heavy metals, such
as lead, cadmium, mercury, or hexavalent chromium, or their compounds,
to be used in the Stabilants and requires the total concentration of these
materials, if present, to be so at a level of less than 100 parts per million
and we so certify. Nor does Stabilant contain any polybrominated biphenyls
(PBBs) or polybrominated diphenyl ethers (PBDEs) and we so certify.
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Ozone Depleting Chemicals: Because of our corporate opposition to
the use of ODC's either in the manufacture of, or as an inclusion in any
of our products, D.W. Electrochemicals Ltd. has consistently refused to
provide any of our products in aerosol spray packaging and/or to supply
any of our materials diluted with any Class 1 ODC, and we so certify.
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PCB's: We certify that this material has been subjected to tests
capable of detecting PCB's to a level of less than 2 parts per million
and no PCB's have been found.
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Packaging: New standards are in place in an attempt to reduce the
amount of plastics, tape and/or adhesives used and to ensure that our packaging
may be reused or recycled
MSDS PREPARATION DATA & EMERGENCY PHONE NUMBER
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Prepared By: Wm Wright
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Department: Engineering
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Preparation Date: January 2nd, 2006
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Current Revision: Revision 21a Updated, and for inclusion on
the web page
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Emergency Phone: (905) 508-7500
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Emergency Contact: Wm Wright
Revision 21a
Patented Canada 1987, US Patent 4696832. Others Pending.
The Stabilants, and the term "Contact Enhancer" ©
Copyrighted 1983.
NATO/CAGE Supplier code #38948
!5 mL Stabilant 22A has NATO Stock Number 5999-21-900-6937
D.W. Electrochemicals Ltd. urges each customer or recipient
of this MSDS to study it carefully to become aware of/and understand the
hazards associated with the product. The reader should consider consulting
reference works or individuals who are experts in ventilation, toxicology
or fire prevention, as necessary or appropriate to use and understand the
data contains in this MSDS.
To promote safe use and handling of this product, each
customer or recipient should (1) notify employees, agents, contractors
and others who may use this material, of the information in this MSDS and
any other information regarding hazards or safety, (2) Furnish this same
information to each customer for the product, and (3) request customers
to notify their employees customers, and other users of the product of
this information.
The information and recommendations contained herein are
based on data believed to be correct, however no guarantee or warranty
of any kind, expressed or implied, is made with respect to information
and recommendations contained herein except when certified
Please refer to Technical Note 1 - MSDS
for Stabilant 22
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